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Title A Study on Influences of Waterproofing Admixtures for Concrete on Self-Healing Properties of Hardened Cement Paste
Authors 김재영 ; 변승호 ; 마상준
Page pp.109-116
ISSN 1229-5515
Keywords 시멘트 ; 에트린자이트 ; 침상 수화물 ; 구체방수재 self-healing ; cement ; ettringite ; fibrous products ; waterproofing admixture
Abstract This study was performed to get information of self-healing mechanism in cement system and the influence of waterproofing admixtures for concrete on self-healing property. For testing, cement paste specimens cured for 7, 14 and 28 days were prepared and crushed into plate-shape pieces. Screened specimens with thickness not more than 1mm were covered with wet rags and cured in a plastic container for 7 and 28 days. After stopping hydration process of the specimens by treatment with acetone, the surfaces of specimens have been contacted with wet rags were analyzed by XRD, DSC, SEM and EDX. The analysis results showed that cement paste has self-healing property and this property is mainly affected by water. Self-healing in cement system is more effective and faster at an early stage of hydration as there is enough content of unreacted cement to make an additional hydration in this period. The results of this study also showed that waterproofing admixtures for concrete have a considerable effect on self-healing of cement pastes; i.e., they improved self-healing effect of cement and, especially, the specimen using admixture C has shown a lot of needle-like or fibrous hydration products which are estimated as ettringite. It is supposed that these ettringite products are effective to enhance self-healing in cement system.